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How can the wavelengths of light be so closely matched with a particular atom or ion?
When an electron jumps from an orbit with low energy to an orbit with higher energy, energy is absorbed by the atom. This produces the dark (absorption) lines in a spectrum (see animation below). When an electron jumps from a higher to a lower orbit, light with a particular wavelength is emitted (see animation below). Since the energy levels in each atom or ion are different, but very well-defined. Since these energy levels determine which wavelengths can be absorbed or emitted, each atom or ion has its own set of spectral lines - its fingerprint. |